The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.74808-09-6, Name is (2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate, molecular formula is C36H36Cl3NO6. In a Article£¬once mentioned of 74808-09-6, Recommanded Product: (2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate
C-GLUCOSYLARENES FROM O-alpha-D-GLUCOSYL-TRICHLOROACETIMIDATES. STRUCTURE OF BERGENIN DERIVATIVES
C-Glucosylation of oxysubstituted benzene derivatives with O-alpha-D-glucopyranosyl trichloroacetimidate gave mainly beta-D-glucopyranosylarenes.The most efficient catalysts were diethyl ether*boron trifluoride, diethyl ether*zinc chloride and zinc chloride.The reaction was successful with fully and partially O-protected phloroglucinols and it was also compatible with an additional C-alkyl substituent.Introduction of an electron-withdrawing, C-acetyl substiuent into the phloroglucinol structure lowered the reactivity.The reaction could be extended to 1,2,3- and 1,2,4-trioxysubstituted benzene derivatives to give the bergenin derivative (3R,4R,4aR,10bS)-3,4-diacetoxy-2-acetoxymethyltetrahydropyrano<5,6-C>-3,4-dihydroisocoumarin via an intramolecular version of this reaction.O-Protected resorcinols and C-substituted derivatives of dioxysubstituted benzenes gave various 4-C-glucosyl-benzene and chroman derivatives.An anomeric mixture of C-glucosyl derivative of anthrone was obtained from 9-trimethylsiloxyantracene (as a monoxysubstituted benzene derivative).The pure beta-D anomer was synthesized from the O-acylated trichloroacetimidate.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 74808-09-6 is helpful to your research., Recommanded Product: (2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics