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PISCICIDAL STEROL ACYLGLUCOSIDES FROM EDGEWORTHIA CHRYSANTA

New potent piscicidal sterol acylglucosides named chrysanthosides have been obtained from the flower of Edgeworthia chrysantha, together with the previously known bis-coumarin and grasshopper ketone and their structures characterized to be sitosterol-3-O-6-linoleoyl- and sitosterol-3-O-6-linolenoyl-beta-D-glucopyranosides by spectral data and synthesis.The natural and synthetic chrysanthosides possess potent piscicidal activity against killie-fish which was killed within 3 hr at a concentration of 0.1 ppm. Keywords: Edgeworthia chrysantha; Thymaaelaeaceae; flower; sitosterol-3-O-6-linoleoyl- and sitosterol-3-O-6-linolenoyl-beta-D-glucopyranoside; grashopper ketone; daphnoretin; piscicidal activity; synthesis of chrysanthoside

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Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics