14215-68-0, Name is N-((2S,3R,4R,5R,6R)-2,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)acetamide, molecular formula is C8H15NO6, belongs to Tetrahydropyrans compound, is a common compound. In a patnet, once mentioned the new application about 14215-68-0, Formula: C8H15NO6
Synthesis of Chiral Building Blocks from D-Glucosamine Hydrochloride
Wittig-reaction of 2-acetamido-2-deoxy-D-glucose (1) with the semistabilized ylide Ph3P=CHPh yielded the epimeric chain-elongated derivatives 2 and 3 in different amounts depending on the reaction conditions.Reaction of 2-(tert-butoxycarbonylamino)-2-deoxy-D-glucose (5) with Ph3P=CHPh yielded the compound 8, or after intramolecular cyclisation, the derivatives 6 or 7.Compound 3 was transformed in three steps into the amino alcohol 10.The 3-amino-1,2-diol derivative 17 and also the N,O-protected alpha-hydroxy-beta-amino acid derivative 16 were obtained from 7.The N-protected homophenylalanine derivatives 12 and 14 were available in two steps from 2 or 8. – Key Words: Amino sugars / Amino alcohols / Amino acids / Wittig reaction
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C8H15NO6. In my other articles, you can also check out more blogs about 14215-68-0
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics