In an article, published in an article, once mentioned the application of 50675-18-8, Name is Tetrahydropyran-4-carbaldehyde,molecular formula is C6H10O2, is a conventional compound. this article was the specific content is as follows.SDS of cas: 50675-18-8
Copper-Catalyzed Substitution of alpha-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
A copper-catalyzed nucleophilic displacement of alpha-triflyloxy nitriles and esters with silicon nucleophiles allows for the stereospecific generation of highly enantioenriched alpha-silylated carboxyl compounds. The enantioselective synthesis of alpha-silylated nitriles is unprecedented. The catalytic system exhibits good functional group tolerance. The stereochemical course of the substitution is shown to proceed with inversion of the configuration. The new reaction is an addition to the still limited number of methods for catalytic C(sp3)-Si cross-coupling.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics