In an article, published in an article, once mentioned the application of 50675-18-8, Name is Tetrahydropyran-4-carbaldehyde,molecular formula is C6H10O2, is a conventional compound. this article was the specific content is as follows.Recommanded Product: Tetrahydropyran-4-carbaldehyde
Iron-catalyzed regioselective transfer hydrogenative couplings of unactivated aldehydes with simple alkenes
An FeBr3-catalyzed reductive coupling of various aldehydes with alkenes that proceeds through a direct hydride transfer pathway has been developed. With iPrOH as the hydrogen donor under mild conditions, previously challenging coupling reactions of unactivated alkyl and aryl aldehydes with simple alkenes, such as styrene derivatives and alpha-olefins, proceeded smoothly to furnish a diverse range of functionalized alcohols with complete linear regioselectivity. The reductive coupling of various aldehydes and alkenes through a direct hydride transfer pathway can be catalyzed by FeBr3. With isopropanol as the hydrogen donor, previously challenging coupling reactions of unactivated alkyl and aryl aldehydes with simple alkenes, such as styrene derivatives and alpha-olefins, proceeded smoothly to furnish a diverse range of functionalized alcohols with complete linear regioselectivity.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics