A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, molecular formula is C12H22O11. In a Article£¬once mentioned of 499-40-1, Recommanded Product: 499-40-1
Abstract: A coper(II) complex, [Cu(dpa) 2(OAc)](ClO 4) (1) [dpa =2 , 2 ?-dipyridylamine; OAc = acetate], has been synthesized and crystallographically characterized. X-ray structure analysis revealed that this mononuclear Cu(II) complex crystallizes as a rare class of hexa coordination geometry named bicapped square pyramidal geometry with P2 1/ c space group. This copper complex displays excellent catalytic efficiency, k cat/ K M(h – 1) = 6.17 ¡Á 10 5 towards the oxidative coupling of 2-aminophenol (2-AP) to aminophenoxazin-3-one. Further, upon stoichiometric addition of copper(II) complex to 3,5-DTBC in presence of molecular oxygen in ethanol medium, the copper complex affords predominantly extradiol cleavage products along with a small amount of benzoquinone and a trace amount of intradiol cleavage products at a rate, k obs= 1.09 ¡Á 10 – 3min – 1, which provide substantial evidence for the oxygen activation mechanism. This paper presents a novel addition of a copper(II) complex having the potential to mimic the active site of phenoxazinone synthase and catechol dioxygenase enzymes with significant catalytic efficiency. Graphical Abstract : SYNOPSIS The mononuclear copper complex having unusual hexa coordination geometry exhibits significant catalytic efficiency, k cat/ K M(h – 1) = 6.17 ¡Á 10 5 towards oxidation of 2-aminophenol which predominantly produced extradiol cleavage products at a rate, k obs= 1.09 ¡Á 10 – 3min – 1 upon addition of 3,5-DTBC in presence of molecular oxygen. [Figure not available: see fulltext.].
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: 499-40-1. In my other articles, you can also check out more blogs about 499-40-1
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics