Discover the magic of the (2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate

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Recommanded Product: (2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. An article , which mentions 74808-09-6, molecular formula is C36H36Cl3NO6. The compound – (2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate played an important role in people’s production and life.

The O-benzyl-protected alpha-glucosyl trichloroacetimidate 1 gives with furan and derivatives and ZnCl2-OEt2 as catalyst via 2-C attack the alpha-C-glucosides 2-alpha – 4-alpha.Good results in this reaction are also obtained with the aryl-substituted glucosyl imidate 5 as glycosyl donor.The alpha-configurations in the products assigned through 1H-NMR data were secured by the reaction of the 2-O-acyl-O-glucosyl trichloroacetimidate 14 with 2-methylfuran. 2′-O-Benzylation of the product provides the C-glucoside 3-beta with beta-configuration, the anomer of compound 3-alpha.The C-glucosylfurans synthesized give with acetylenedicarboxylate cycloadducts, they undergo electrophilic substitution at the 5-position, and they are directly C-lithiated with lithium diisopropylamide.The corresponding C-glucosylation of thiophene and 2-methylthiophene with the trichloroacetimidate 1 provide the alpha-C-glucosides 15-alpha and 16-alpha whereas 1,2-dimethylindole lead to the corresponding beta-C-glucoside 18-beta.

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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics