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Palladium(0)-catalyzed reaction of various carbohydrates derived from glucofuranose, mannofuranose, ribofuranose, glucopyranose, and glucosamine, beating a free hydroxyl group, with 1,4-bis-(methoxycarbonyloxy)but-2-ene afforded the corresponding bis-glycosides of butene-1,4-diol. Hydrogenation in the presence of palladium on charcoal of these unsaturated compounds led to the formation of the bis-glycosides of butane-1,4-diol. The condensation was successfully extended to the bis-carbonate of 1,2-bis-[(1-hydroxy)propen-2-yl]benzene and derivatives of glucofuranose, ribofuranose and glucosamine.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Computed Properties of C14H20O10, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 10343-06-3, in my other articles.
Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics