If you are interested in 499-40-1, you can contact me at any time and look forward to more communication.Electric Literature of 499-40-1
Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice can avoid electrode passivation, which strongly inhibit the efficient activation of substrates. 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, molecular formula is C12H22O11. In a Article,once mentioned of 499-40-1, Electric Literature of 499-40-1
The tetradentate ligands 1,8-bis(pyrid-2-yl)-3,6-dithiaoctane (pdto) and 1,8-bis(benzimidazol-2-yl)-3,6-dithiaoctane (bbdo) form the complexes Ru(pdto)(mu-Cl)2(ClO4)2 1 and Ru(bbdo)(mu-Cl)2(ClO4)2 2 respectively. The new di-mu-chloro dimers 1 and 2 undergo facile symmetrical bridge cleavage reactions with the diimine ligands 2,2?-bipyridine (bpy) and dipyridylamine (dpa) to form the six-coordinate complexes Ru(pdto)(bpy)(ClO 4)2 3, Ru(bbdo)(bpy)(ClO4)2 4, Ru(pdto)(dpa)(ClO4)2 5 and Ru(bbdo)(dpa)(ClO 4)2 6 and with the triimine ligand 2,2?:6,2?- terpyridine (terpy) to form the unusual seven-coordinate complexes Ru(pdto)(terpy)(ClO4)2 7 and Ru(bbdo)(terpy)(ClO 4)2 8. In 1 the dimeric cation Ru(pdto)(mu-Cl) 22+ is made up of two approximately octahedrally coordinated Ru(ii) centers bridged by two chloride ions, which constitute a common edge between the two Ru(ii) octahedra. Each ruthenium is coordinated also to two pyridine nitrogen and two thioether sulfur atoms of the tetradentate ligand. The ligand pdto is folded around Ru(ii) as a result of the cis-dichloro coordination, which corresponds to a “cis-alpha” configuration DeltaDelta/LambdaLambda (rac) diastereoisomer supporting the possibility of some attractive pi-stacking interactions between the parallel py rings at each ruthenium atom. The ruthenium atom in the complex cations 3a and 4 exhibit a distorted octahedral coordination geometry composed of two nitrogen atoms of the bpy and the two thioether sulfur and two py/bzim nitrogen atoms of the pdto/bbdo ligand, which is actually folded around Ru(ii) to give a “cis-alpha” isomer. The molecule of complex 5 contains a six-coordinated ruthenium atom chelated by pdto and dpa ligands in the expected distorted octahedral fashion. The 1H and 13C NMR spectral data of the complexes throw light on the nature of metal-ligand bonding and the conformations of the chelate rings, which indicates that the dithioether ligands maintain their tendency to fold themselves even in solution. The bis-mu-chloro dimers 1 and 2 show a spin-allowed but Laporte-forbidden t 2g6 (1A1g) ? t 2g5 eg1 (1T1g, 1T2g) d-d transition. They also display an intense Ru(ii) dpi ? py/bzim (pi*) metal-to-ligand charge transfer (MLCT) transition. The mononuclear complexes 3-8 exhibit dpi ? pi* MLCT transitions in the range 340-450 nm. The binuclear complexes 1 and 2 exhibit a ligand field (3MC) luminescence even at room temperature, whereas the mononuclear complexes 3 and 4 show a ligand based radical anion ( 3MLCT) luminescence. The binuclear complexes 1 and 2 undergo two successive oxidation processes corresponding to successive Ru(ii)/Ru(iii) couples, affording a stable mixed-valence RuIIRuIII state (Kc: 1, 3.97 × 106; 2, 1.10 × 106). The mononuclear complexes 3-7 exhibit only one while 8 shows two quasi-reversible metal-based oxidative processes. The coordinated ‘soft’ thioether raises the redox potentials significantly by stabilising the ‘soft’ Ru(ii) oxidation state. One or two ligand-based reduction processes were also observed for the mononuclear complexes. The Royal Society of Chemistry 2006.
If you are interested in 499-40-1, you can contact me at any time and look forward to more communication.Electric Literature of 499-40-1
Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics