In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction. 31608-22-7, Name is 2-(4-Bromobutoxy)tetrahydro-2H-pyran, molecular formula is C9H17BrO2. In a Article，once mentioned of 31608-22-7, Reference of 31608-22-7
A new strategy for the synthesis of alpha-hydroxy ketones by samarium(II) iodide-mediated three-component coupling of organic halides, an isocyanide, and carbonyl compounds is disclosed.An (alpha-iminoalkyl)samarium(III) species is generated in situ by treatment of an organic halide with 2 equiv of samarium(II) iodide in the presence of 2,6-xylyl isocyanide.Subsequent treatment of the mixture with a carbonyl compound affords alpha-hydroxy imines, which are converted by acid-catalyzed hydrolysis to the corresponding alpha-hydroxy ketones.The mild reaction conditions employed are compatible with a variety of functionalities including terminal acetylenes and trimethylsilyl ethers.Application of the method to the synthesis of alpha-hydroxy aldehydes is also presented.
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Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics