Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 97739-46-3, is researched, SMILESS is CC1(C2)OC(C3)(C)OC2(C)OC3(C)P1C4=CC=CC=C4, Molecular C16H21O3PJournal, Catalysis Science & Technology called Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene, Author is Fuentes, Jose A.; Slawin, Alexandra M. Z.; Clarke, Matthew L., the main research direction is palladium trioxo adamantyl cage phosphine chloride complex catalysts; alkoxycarbonylation styrene palladium catalyzed tert butoxycarbonylation styrene.COA of Formula: C16H21O3P.
Pre-catalysts of type [PdCl(allyl)(monophosphine)] where the monophosphine is one of the tri-oxo-adamantyl cage phosphines such as 1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxo-6-phospha-adamantane give very high reactivity in the regioselective hydroxycarbonylation and alkoxycarbonylation (hydro-esterification) of styrene at 60 °C. This high reactivity enables the use of tert-butanol as nucleophile in the alkoxycarbonylation of styrene.
I hope my short article helps more people learn about this compound(1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane)COA of Formula: C16H21O3P. Apart from the compound(97739-46-3), you can read my other articles to know other related compounds.
Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics