HPLC of Formula: 97739-46-3. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane, is researched, Molecular C16H21O3P, CAS is 97739-46-3, about Complex Polyheterocycles and the Stereochemical Reassignment of Pileamartine A via Aza-Heck Triggered Aryl C-H Functionalization Cascades. Author is Jones, Benjamin T.; Garcia-Carceles, Javier; Caiger, Lewis; Hazelden, Ian R.; Lewis, Richard J.; Langer, Thomas; Bower, John F..
Structurally complex benzo- and spiro-fused N-polyheterocycles can be accessed via intramol. Pd(0)-catalyzed alkene 1,2-aminoarylation reactions. The method uses N-(pentafluorobenzoyloxy)carbamates as the initiating motif, and this allows aza-Heck-type alkene amino-palladation in advance of C-H palladation of the aromatic component. The chem. is showcased in the first total synthesis of the complex alkaloid (+)-pileamartine A, I, which has resulted in the reassignment of its absolute stereochem.
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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics