So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Quintero-Duque, Samuel; Fleischer, Ivana researched the compound: 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane( cas:97739-46-3 ).Electric Literature of C16H21O3P.They published the article 《Tandem and One-Pot Hydroformylation/Michael Reactions of Acrylates》 about this compound( cas:97739-46-3 ) in Synthesis. Keywords: hydroformylation Michael tandem acrylate rhodium catalyst; carbonyl compound preparation tandem hydroformylation Michael aldol rhodium catalyst. We’ll tell you more about this compound (cas:97739-46-3).
The combination of various reactions in one operational step leads to many advantages in synthetic strategies, such as a lower consumption of resources, effort, and time, when intermittent workup and purification steps can be avoided. The hydroformylation reaction of acrylates gives access to 2-formylpropanoates, which, thanks to their structural features, constitute useful intermediates in the synthesis of more complex compounds Herein, we report a simple and convenient one-pot strategy to synthesize functionalized carbonyl compounds starting from these readily available substrates, via tandem or one-pot hydroformylation, Michael addition, and aldol reactions.
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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics