So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Danklmaier, Johann; Hoenig, Helmut researched the compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine( cas:82954-65-2 ).Related Products of 82954-65-2.They published the article 《Syntheses and structures of diastereomerically pure 2,6-disubstituted 3-morpholinones》 about this compound( cas:82954-65-2 ) in Liebigs Annalen der Chemie. Keywords: morpholinone disubstituted diastereomerically pure. We’ll tell you more about this compound (cas:82954-65-2).
The syntheses of the hitherto unknown diastereomerically pure 2,6-disubstituted 3-morpholinones I [R = Me, CH2OH, (CH2)3OH] are described. The necessary educts, the optically active amino alcs. (S)-H2NCH2CH(OH)CH2OH and (S)-H2NCH2CH(OH)(CH2)3OH are synthesized by improved or new procedures. A two-step synthetic sequence via the 2-chloro-N-(2-hydroxyethyl)carboxamides leads to products much purer than those obtained by the known direct condensation of amino alcoholates with α-halogeno carboxylic esters. The structures of the title compounds are characterized by their NMR spectra.
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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics