The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 2-Chloro-1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium chloride(SMILESS: CC(C1=C([N+]2=C(Cl)N(C3=C(C(C)C)C=CC=C3C(C)C)C=C2)C(C(C)C)=CC=C1)C.[Cl-],cas:1228185-09-8) is researched.Quality Control of 1-Bromo-2-pentyne. The article 《Triazenyl Radicals Stabilized by N-Heterocyclic Carbenes》 in relation to this compound, is published in Journal of the American Chemical Society. Let’s take a look at the latest research on this compound (cas:1228185-09-8).
Notwithstanding the notable progress in the synthesis of N-heterocyclic carbene-stabilized radicals, aminyl radicals, supported by NHCs or otherwise, were scarcely studied due to synthetic challenges. Triazenyl radical is a particular form of aminyl radical that contains three adjacent N atoms, and offers intriguing possibilities for unique reactivity and phys. properties stemming from expected delocalization of the spin d. over the NNN moiety and its conjugated substituents. Here, the authors report the synthesis and full characterization of the 1st NHC-stabilized triazenyl radicals, obtained by 1-electron reduction of the corresponding triazenyl cations with K metal. These radicals reversibly oxidize back to the cations upon treatment with transition metal sources or electrophiles, and abstract H atom from xanthene to form a new N-H bond at the center N atom. Potential application of the redox couple between triazenyl cation and triazenyl radical was demonstrated as cathode active materials in Li ion batteries.
This literature about this compound(1228185-09-8)SDS of cas: 1228185-09-8has given us a lot of inspiration, and I hope that the research on this compound(2-Chloro-1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium chloride) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics