Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1228185-09-8, is researched, SMILESS is CC(C1=C([N+]2=C(Cl)N(C3=C(C(C)C)C=CC=C3C(C)C)C=C2)C(C(C)C)=CC=C1)C.[Cl-], Molecular C27H36Cl2N2Journal, Article, Chemical Communications (Cambridge, United Kingdom) called Synthesis of P2C2O2 and P2CO via NHC-mediated coupling of the phosphaethynolate anion, Author is Gilliard, Robert J.; Suter, Riccardo; Schrader, Erik; Benko, Zoltan; Rheingold, Arnold L.; Grutzmacher, Hansjorg; Protasiewicz, John D., the main research direction is heterocyclic carbene mediated coupling phosphaethynolate anion; crystal structure mol phosphorus heterocycle diphosphorus compound optimized.Application of 1228185-09-8.
The reaction of the chloroimidazolium chloride salt, [NHC-Cl][Cl], NHC = C{N(2,6-iPr2C6H3)CH}2 (1) with two equivalent of sodium phosphaethynolate, Na[OCP]·(dioxane)2.5, results in the formation of NHC-{cyclo-(CO)-P2-C(O)} (2) and NHC-P2-C(O)-NHC (3). Notably, in the presence of free NHC ligand, compound 2 converts to compound 3 via extrusion of CO at elevated temperatures The nature of the bonding in these complexes was probed computationally and spectroscopically.
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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics