Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Catalysis Science & Technology called A modular family of phosphine-phosphoramidite ligands and their hydroformylation catalysts: steric tuning impacts upon the coordination geometry of trigonal bipyramidal complexes of type [Rh(H)(CO)2(P-P*)], Author is How, Rebecca C.; Hembre, Robert; Ponasik, James A.; Tolleson, Ginette S.; Clarke, Matthew L., which mentions a compound: 97739-46-3, SMILESS is CC1(C2)OC(C3)(C)OC2(C)OC3(C)P1C4=CC=CC=C4, Molecular C16H21O3P, Related Products of 97739-46-3.
Four new ferrocene-based planar-chiral phosphine-phosphoramidite bidentate ligands I (1-4; R = Me, PhCH2, R1 = Me, tBu; R2 = Me, tBu; R3 = H, Me) have been synthesized and studied in rhodium-catalyzed hydroformylation. Variable temperature NMR studies have been used along with HPIR to investigate the coordination mode of the trigonal bipyramidal complexes formed from [Rh(acac)(CO)2], ligand and syngas. It was found that small changes to the ligand structure have a large effect on the geometry of the active catalytic species. The rhodium catalysts of these new ligands were found to give unusually high iso-selectivity in the hydroformylation of propene and 1-octene.
After consulting a lot of data, we found that this compound(97739-46-3)Related Products of 97739-46-3 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics