Archives for Chemistry Experiments of 2,3,4,6-Tetra-o-acetyl-D-glucopyranose

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Application of 10343-06-3. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 10343-06-3, Name is 2,3,4,6-Tetra-o-acetyl-D-glucopyranose

Generation of near-enantiopure alpha-alkyl alpha-formyl alpha-hydroxy ketones/esters and their interception with ethoxycarbonylmethylenetriphenylphosphorane

Two protocols for the generation of the (R)-enantiomers of alpha-alkyl alpha- formyl alpha-hydoxy ketones/esters in states of high enantiomeric purity are developed; the formyl functions of such compounds undergo Wittig condensations with ethoxycarbonylmethylenetriphenylphosphorane in dimethyl sulfoxide to afford the corresponding alkenes with high (E)- stereoselectivities and with e.e.s of 91-99%.

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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics