Discovery of N-((2S,3R,4R,5R,6R)-2,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)acetamide

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Reference of 14215-68-0. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 14215-68-0, Name is N-((2S,3R,4R,5R,6R)-2,4,5-Trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)acetamide. In a document type is Article, introducing its new discovery.

Aniphiphilic and mesogenic carbohydrates. 10. Change of the type of the mesophase by variation of the acyl chain of amphiphilic tetradecyl (N-acylamino)-2-deoxy-1-thio-beta-D-glucopyranosides

The homologous amphiphilic tetradecyl-2-(N-alkanoylamino)-2-deoxy-1-thio-beta-D-glucopyranosides 5a-f were synthesized from the 2-(N-alkanoylamino)-2-deoxy-D-glucopyranoses 1a-f via the glucosyl chlorides 2a-f, the glucosyl isothiuronium chlorides 3a-f, and the acetylated thioglucosides 4a-f. On heating the amphiphiles 5a-f form different types of liquid crystalline phases in dependence of the length of the acyl chain, i.e. 5a and 5b form smectic phases, 5d-f form columnar mesophases. Polarisation microscopy, DSC-measurements and contact preparations were used to characterise the liquid crystalline phases.

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Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics