Related Products of 499-40-1. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal
Selective Photooxidation of Sulfides Catalyzed by Bis-cyclometalated IrIII Photosensitizers Bearing 2,2?-Dipyridylamine-Based Ligands
A new family of heteroleptic bis-cyclometalated IrIII complexes with formula [Ir((Formula presented.))2((Formula presented.))]Cl ((Formula presented.) =2-phenylpyridinate and (Formula presented.) =2,2?-dipyridylamine or N-benzylated 2,2?-dipyridylamines, were synthesized, characterized, and successfully used as photosensitizers in the catalytic photooxidation of an array of dialkyl, dibenzyl, alkyl aryl, and diaryl sulfides, as well as sulfur-containing amino acids. Furthermore, the reactions proceeded with optimal chemoselectivity, and atom economy under mild conditions. Experimental observations support a dual mechanism in which singlet oxygen and superoxide are the actual oxidants.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics