Application of 585-88-6, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 585-88-6, Name is Maltitol, SMILES is OC[C@H](O)[C@@H](O)[C@H](O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1)[C@H](O)CO, belongs to Tetrahydropyrans compound. In a article, author is Zhu, Rui, introduce new discover of the category.
Cascade conversion of furancarboxylic acid to butanediol diacetate over Pd/C and La(OTf)(3) catalytic system
The conversion of biomass to a high value-added product 1, 4-butanediol (BDO) and its derivatives is of great economic significance. In this work, furancarboxylic acid (FCA) was adopted as the raw material to prepare BDO. The one-pot synthesis of 1, 4-butanediol diacetate (BDA) has been successfully prepared from FCA with metal triflates and Pd/C catalysts. The effect of reaction conditions was investigated and the reaction routes was systematically studied by H-1-NMR and GC. The tandem catalytic process from FCA to BDA mainly underwent three stages. Firstly, FCA was hydrogenated to tetrahydrofurfuric acid (THFCA) by Pd/C. Afterwards, THFCA was decarbonylated to form oxonium ions with metal triflates. Then the oxonium ions was rapidly hydrogenated to form tetrahydrofuran (THF) by Pd/C. Ultimately, THF was ring-opening esterified to BDA by metal triflates. This novel synthesis method of BDO from FCA provides a promising protocol for broadening the application of common biomass substrates.
Application of 585-88-6, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 585-88-6 is helpful to your research.
Reference:
Tetrahydropyran – Wikipedia,
,Tetrahydropyran – an overview | ScienceDirect Topics