A new application about 108-55-4

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Rubidium and Cesium Enediamide Complexes Derived from Bulky 1,4-Diazadienes

The first rubidium and cesium enediamide complexes based on bulky 1,4-diaza-1,3-diene ligands (DADs) have been prepared by metalation of either 1,4-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene (1, = (H2)DAD(Dipp)) or 1,4-bis(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene (2, = (Me2)DAD(Dipp)) with an excess of Rb or Cs metals in coordinating solvents such as tetrahydrofuran (THF) or 1,2-dimethoxyethane (DME). All new complexes were fully characterized by spectroscopic and analytical methods as well as single-crystal X-ray diffraction studies.

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Reference:
Tetrahydropyran – Wikipedia,
,Tetrahydropyran – an overview | ScienceDirect Topics