In an article, published in an article, once mentioned the application of 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal,molecular formula is C12H22O11, is a conventional compound. this article was the specific content is as follows.name: (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal
The reaction of AgNO3 and sulfobenzoate with neutral ligands led to the formation of three complexes, {[Ag2(4-sb)(Ph 3P)2(3-apy)]¡¤(H2O)}n (1), {[Ag(PPh3)(2-apy)]¡¤[Ag(PPh3)(3-sb)]¡¤(H 2O)}n (2) and [Ag(PPh3)(Hdpa)(4-Hsb)] (3) (4-H2sb = 4-sulfobenzoic acid, PPh3 = triphenylphosphine, 3-apy = 3-aminopyridine, 2-apy = 2-aminopyridine, 3-H2sb = 3-sulfobenzoic acid, Hdpa = 2,2?-dipyridylamine) Complex 1 is a 2D sandwich-like polymer. Complex 2 is a cation-anion species and has a 1D polymer structure. Complex 3 is a monomer. Complexes 1-3 contain the Ag-PPh3 unit and such unit largely hinders the Ag-Ag, pi…pi, Ag…pi, and Ag…C interactions. The experimental results indicated that these three complexes have weaker conductivities than those corresponding silver complexes having abundant weak interactions, especially pi…pi and Ag-Ag interactions, illustrating that the cation-anion species having potential ability of charge transfer can largely promote the conductivity property. Copyright
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics