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The 77 K absorption, emission, excitation, photoselection, and time-resolved emission spectra and emission lifetimes were obtained in aprotic and protic systems for the series of complexes 2+ (n = 0-3) and 2+ (n = 0-3).The n = 2 species have d-?* MLCT emission characteristics indicative of the Ru-bpy and Ru-phen chromophores as do the n = 1 species in water, but in weak hydrogen-bonding solvents, as well as aprotic solvents, a second emission is observed producing a dual luminescence for the n = 1 species.This second emission is assigned to an nHDPA-?bpy* (or nHDPA-?phen*) interligand charge-transfer (ILCT) process.The absorption spectra for the deprotonated species (n-1)+ (n = 1, 2) were also obtained, and the absence of emission up to 800 nm for these complexes is discussed in terms of available emitting states and metal perturbations.

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Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics