Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 2081-44-9, Name is Tetrahydro-2H-pyran-4-ol, molecular formula is C5H10O2. In a Article，once mentioned of 2081-44-9, Formula: C5H10O2
The proton resonance spectra of tetrahydropyran, at room temperature and -85C where the ring inversion is slow on the NMR timescale, 2-methoxy-, 3-methyl- and several 4-substituted tetrahydropyrans, 2-methyl-1,3-dioxolane and the rigid cyclic ethers 7-oxabicyclo[2.2.1]heptane and 1,8-cineole heve been recorded and completely analysed. These results together with literature data on acyclic and cyclic ethers (1,3- and 1,4-dioxane, dioxolane, 4-oxa-5alpha-androstane etc.) have allowed the determination of the oxygen substituent chemical shifts (SCS) in these systems. This data set consisting of 78 proton chemical shifts in 17 compounds has been used to test the application of a previous theoritical model of proton chemical shifts to these compounds. It is shown that the model gives a very good account of the proton chemical shifts in these systems. The ether oxygen SCS are due to both steric and electrostatic terms, the steric term predominating at short distances (e.g. in the 1,3-diaxial interactions in methoxycyclohexanes). Conformational isomerism in these compounds has also been investigated. Low temperature NMR gave DeltaG (eq-ax) + 1.0 kcal mol-1 for 4 hydroxy-THP. Analysis of the couplings in the CHCH2OH side chain of 2-(hydroxymethyl)-THP has shown that the preferred conformer is gt in both chloroform and acetone solvents.
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Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics