So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Aguilar Troyano, Francisco Jose; Ballaschk, Frederic; Jaschinski, Marcel; Oezkaya, Yasemin; Gomez-Suarez, Adrian researched the compound: 1-Bromo-2-pentyne( cas:16400-32-1 ).HPLC of Formula: 16400-32-1.They published the article 《Light-Mediated Formal Radical Deoxyfluorination of Tertiary Alcohols through Selective Single-Electron Oxidation with TEDA2+.》 about this compound( cas:16400-32-1 ) in Chemistry – A European Journal. Keywords: alc tertiary Selectfluor photochem radical deoxyfluorination; tertiary alkyl fluoride preparation; fluorination; mechanistic studies; organic synthesis; photochemistry; radicals. We’ll tell you more about this compound (cas:16400-32-1).
The synthesis of tertiary alkyl fluorides through a formal radical deoxyfluorination process was described. This light-mediated, catalyst-free methodol. was fast and broadly applicable allowing for the preparation of C-F bonds from (hetero)benzylic, propargylic and non-activated tertiary alc. derivatives Preliminary mechanistic studies supported that the key step of the reaction is the single-electron oxidation of cesium oxalates-which are readily available from the corresponding tertiary alcs.-with in situ generated TEDA2+ (TEDA: N-(chloromethyl)triethylenediamine), a radical cation derived from Selectfluor.
There is still a lot of research devoted to this compound(SMILES：CCC#CCBr)HPLC of Formula: 16400-32-1, and with the development of science, more effects of this compound(16400-32-1) can be discovered.
Reference:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics