Kikukawa, Kiyoshi’s team published research in Chemistry Letters in | CAS: 27943-46-0

Chemistry Letters published new progress about 27943-46-0. 27943-46-0 belongs to tetrahydropyran, auxiliary class Tetrahydropyran,Alkynyl,Ether, name is 2-((2-Methylbut-3-yn-2-yl)oxy)tetrahydro-2H-pyran, and the molecular formula is C10H16O2, Application In Synthesis of 27943-46-0.

Kikukawa, Kiyoshi published the artcileRegioselective hydrostannation of terminal acetylenes under transition metal catalysis, Application In Synthesis of 27943-46-0, the publication is Chemistry Letters (1988), 881-4, database is CAplus.

Rhodium complexes [RhClL3, RhCl(CO)L2 (L = PPh3)], [RhCl(COD)]2 (COD = 1,5-cyclooctadiene)] catalyze the hydrostannylation of terminal acetylenes, RCCH (R = Ph, Me3Si, etc.) with Bu3SnH to produce RC(SnBu3):CH2 selectively. Other transition metal complexes [MCl2L2 (M = Ni, Pd, Pt, Co)] are also active for the hydrostannylation, but with less selectivity.

Chemistry Letters published new progress about 27943-46-0. 27943-46-0 belongs to tetrahydropyran, auxiliary class Tetrahydropyran,Alkynyl,Ether, name is 2-((2-Methylbut-3-yn-2-yl)oxy)tetrahydro-2H-pyran, and the molecular formula is C10H16O2, Application In Synthesis of 27943-46-0.

Referemce:
https://en.wikipedia.org/wiki/Tetrahydropyran,
Tetrahydropyran – an overview | ScienceDirect Topics