Crystallization of glucose. I. Theoretical principles of solid-phase separation was written by Cabafi, Klara. And the article was included in Hemijska Industrija in 1973.Synthetic Route of C6H14O7 This article mentions the following:
The rate of crystallization and the purity of separated crystals of D-glucose monohydrate (I) [14431-43-7] depended on the operating temperature, the solution viscosity, the purity of the solution, the supersaturation, the amount of seeding crystals added, and the cooling rate. The α-isomer of I was less soluble in the aqueous solution and thus preferentially precipitated after seeding. Above 60.deg., any saccharose [57-50-1] present was preferentially soluble in H2O and therefore did not precipitate with the I. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Synthetic Route of C6H14O7).
(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Tetrahydropyran is a useful synthetic intermediate. Tetrahydropyranyl (THP-) ethers derived from the reaction of alcohols and dihydropyran are common intermediates in organic synthesis. The most notable anticancer agent, bryostatin, and eribulin are marine macrolides having intriguing tetrahydropyran and furan motif. Synthetic Route of C6H14O7
Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics