499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, belongs to Tetrahydropyrans compound, is a common compound. 499-40-1In an article, authors is Anderson, Peter A., once mentioned the new application about 499-40-1.
Designed Synthesis of Mononuclear Tris(heteroleptic) Ruthenium Complexes Containing Bidentate Polypyridyl Ligands
A general synthetic methodology is reported for tris(bidentate)ruthenium(II) complexes containing three different polypyridyl ligands, based onthe sequential addition of the ligands to the oligomer [Ru(CO)2Cl2]n. The tris(heteroleptic) complexes were characterized by FAB mass spectrometry and NMR spectroscopy. An X-ray crystal structure determination was made for the complex [Ru(Me2bpy)(phen)(bpa)](PF6)2.C6H14 [C40H43F12N7P2Ru, M = 1062.8; Me2bpy = 4,4′-dimethyl-2,2′-bipyridine, phen = 1,10-phenanthroline, bpa = bis(2-pyridyl)amine]: triclinic, space group P1-, a = 14.57(3) A, b = 13.50(3) A, c = 12.73(3) A, alpha = 68.6(2)¡ã, beta = 63.5(1)¡ã, gamma = 79.8(2)¡ã, V = 2082 A**3, Z = 2. Aspects of the electrochemistry, spectroscopy, and photophysics of the tris(heteroleptic) species are discussed.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics