In an article, published in an article, once mentioned the application of 10034-20-5, Name is (2S,3R,4R,5S,6R)-6-(Acetoxymethyl)-3-aminotetrahydro-2H-pyran-2,4,5-triyl triacetate hydrochloride,molecular formula is C14H22ClNO9, is a conventional compound. this article was the specific content is as follows.Safety of (2S,3R,4R,5S,6R)-6-(Acetoxymethyl)-3-aminotetrahydro-2H-pyran-2,4,5-triyl triacetate hydrochloride
THE REACTION OF 2-AMINO-2-DEOXYHEXOPYRANOSES WITH ISOCYANATES. SYNTHESIS OF UREAS AND THEIR TRANSFORMATION INTO HETEROCYCLIC DERIVATIVES.
The reactions of 2-amino-2-deoxyglycopyranoses with aryl isocyanates have been investigated in detail and ureas and heterocyclic derivatives are obtained.The mechanism of formation of glycofurano<2,1-d>imidazolidin-2-ones 62 has now become visible, while previous reports and the classical literature dealing with the subject in question proposed alternative structures for the reaction products.The reactions are pH-dependent and only furanoid bicycles are smoothly obtained at acidic pH values, whereas in neutral or basic media 5-hydroxyimidazolidin-2-one derivatives 66 can be isolated.These monocyclic structures appear to be the true intermediates of the reaction and, under appropriate conditions, can be converted exclusively into the corresponding cis fused five-membered ring systems.Likewise, the first cis-fused glycopyrano<2,1-d>imidazolidin-2-ones 75 have been also prepared.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics