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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, is researched, Molecular C6H13NO2, CAS is 82954-65-2, about Direct conversion of (R)-epichlorohydrin to (S)-3-aminopropane-1,2-diol: an important chiral C-3 building block.Safety of (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine.

A new and effective method for the preparation of (S)-3-amino-1,2-propanediol was established starting from (R)-epichlorohydrin. The synthetic approach involves the reaction of (R)-epichlorohydrin with acetone catalyzed by BF3·OEt2 to give (R)-4-(chloromethyl)-2,2-dimethyl-1,3-dioxolane. Subsequent replacement of the Cl with NH2 group by azidation followed by reduction gave ((S)-2,2-dimethyl-1,3-dioxolan-4-yl)methanamine, which was converted into (S)-3-aminopropane-1,2-diol·HCl by acetal deprotection with MeOH·HCl.

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Synthetic Route of C6H13NO2. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, is researched, Molecular C6H13NO2, CAS is 82954-65-2, about Self-assembly of small-molecule fumaramides allows transmembrane chloride channel formation. Author is Roy, Arundhati; Gautam, Amitosh; Malla, Javid Ahmad; Sarkar, Sohini; Mukherjee, Arnab; Talukdar, Pinaki.

This study reports the formation of self-assembled transmembrane anion channels by small-mol. fumaramides. Such artificial ion channel formation was confirmed by ion transport across liposomes and by planar bilayer conductance measurements. The geometry-optimized model of the channel and Cl- ion selectivity within the channel lumen was also illustrated.

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The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, is researched, Molecular C6H13NO2, CAS is 82954-65-2, about Helical supramolecular organization of a 1,2-diol appended naphthalene diimide organogelator via an extended intermolecular H-bonding network, the main research direction is naphthalene diimide organogelator preparation self assembly supramol organization.Application In Synthesis of (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine.

Self-assembly of a 1,2-diol appended naphthalene diimide derivative featuring chiral and J-type aggregation was reported. In methylcyclohexane/CHCl3, the compound exhibited intense yellow excimer and thermoreversible “”sol-gel”” behavior. Morphol. and CD studies revealed long range M-helical nanofibre formation. A theor. model of the cooperative hydrogen bonding was also proposed.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 82954-65-2, is researched, SMILESS is NC[C@@H]1OC(C)(C)OC1, Molecular C6H13NO2Journal, Tetrahedron called A flexible route to new spirodioxanes, oxathianes, and morpholines, Author is Goubert, Marlene; Canet, Isabelle; Sinibaldi, Marie-Eve, the main research direction is dichloropropanone benzyloxime solketal iterative nucleophilic substitution; oxime ether diketal derivative preparation deprotection spiroacetalization; dioxaspiroundecane azathia derivative stereoselective preparation; azatrioxaspiroundecane derivative stereoselective preparation; thiatrioxaspiroundecane derivative stereoselective preparation.Application In Synthesis of (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine.

This work describes a modular efficient route to 10-aza-4-thia-, 10-aza-4-oxa-, and 10-oxa-4-thia-1,7-dioxaspiro[5.5]undecanes. The synthetic pathway relies upon the iterative nucleophilic substitution of 1,3-dichloropropan-2-one O-benzyloxime by solketal derivatives The oxime key-intermediates, submitted to an acidic deprotection-spiroacetalization process, afforded these original spiroketal compounds in three steps, few purifications, and very good yields.

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Reference of (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, is researched, Molecular C6H13NO2, CAS is 82954-65-2, about Efficient pathways to (R)- and (S)-5-hydroxymethyl-2-oxazolidinone and some derivatives. Author is Danielmeier, Karsten; Steckhan, Eberhard.

Two new syntheses of enantiomerically pure (R)- and (S)-5-hydroxymethyl-2-oxazolidinone have been developed starting with D-mannitol, L-ascorbic acid and (R)- or (S)-malic acid. (R)- and (S)-5-hydroxymethyl-2-oxazolidinone have been used to synthesize some new homochiral 2-oxazolidinone derivatives

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Related Products of 82954-65-2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, is researched, Molecular C6H13NO2, CAS is 82954-65-2, about A practical approach to the synthesis of enantiomerically pure 2,6-disubstituted morpholines under phase transfer catalysis conditions. Author is Albanese, D.; Foschi, F.; Penso, M..

A novel, straightforward and high yielding synthesis of enantiomerically pure 2,6-disubstituted morpholines, e.g. I, has been developed through the regioselective cyclization of diols, e.g. II. Cyclization precursors have been obtained by the ring opening of com. available chiral epoxides under solid-liquid phase transfer catalysis conditions (SL-PTC).

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HPLC of Formula: 82954-65-2. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, is researched, Molecular C6H13NO2, CAS is 82954-65-2, about Self-assembly of small-molecule fumaramides allows transmembrane chloride channel formation. Author is Roy, Arundhati; Gautam, Amitosh; Malla, Javid Ahmad; Sarkar, Sohini; Mukherjee, Arnab; Talukdar, Pinaki.

This study reports the formation of self-assembled transmembrane anion channels by small-mol. fumaramides. Such artificial ion channel formation was confirmed by ion transport across liposomes and by planar bilayer conductance measurements. The geometry-optimized model of the channel and Cl- ion selectivity within the channel lumen was also illustrated.

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In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called A practical approach to the synthesis of enantiomerically pure 2,6-disubstituted morpholines under phase transfer catalysis conditions, published in 2009-02-14, which mentions a compound: 82954-65-2, Name is (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, Molecular C6H13NO2, Electric Literature of C6H13NO2.

A novel, straightforward and high yielding synthesis of enantiomerically pure 2,6-disubstituted morpholines, e.g. I, has been developed through the regioselective cyclization of diols, e.g. II. Cyclization precursors have been obtained by the ring opening of com. available chiral epoxides under solid-liquid phase transfer catalysis conditions (SL-PTC).

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The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine, is researched, Molecular C6H13NO2, CAS is 82954-65-2, about A practical approach to the synthesis of enantiomerically pure 2,6-disubstituted morpholines under phase transfer catalysis conditions, the main research direction is disubstituted morpholine preparation regioselective cyclization transfer catalysis.Reference of (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine.

A novel, straightforward and high yielding synthesis of enantiomerically pure 2,6-disubstituted morpholines, e.g. I, has been developed through the regioselective cyclization of diols, e.g. II. Cyclization precursors have been obtained by the ring opening of com. available chiral epoxides under solid-liquid phase transfer catalysis conditions (SL-PTC).

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The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: (S)-(2,2-dimethyl-[1,3]-dioxolan-4-yl)-methylamine( cas:82954-65-2 ) is researched.Recommanded Product: 82954-65-2.Schade, Boris; Singh, Abhishek Kumar; Wycisk, Virginia; Cuellar-Camacho, Jose Luis; von Berlepsch, Hans; Haag, Rainer; Boettcher, Christoph published the article 《Stereochemistry-Controlled Supramolecular Architectures of New Tetrahydroxy-Functionalized Amphiphilic Carbocyanine Dyes》 about this compound( cas:82954-65-2 ) in Chemistry – A European Journal. Keywords: amphiphilic cyanine dye J aggregate chirality; chirality; dyes/pigments; hydrogen bonds; supramolecular chemistry; synthesis design. Let’s learn more about this compound (cas:82954-65-2).

The syntheses of novel amphiphilic 5,5′,6,6′-tetrachlorobenzimidacarbocyanine (TBC) dye derivatives with aminopropanediol head groups, which only differ in stereochem. (chiral enantiomers, meso form and conformer), are reported. For the achiral meso form, a new synthetic route towards asym. cyanine dyes was established. All compounds form J aggregates in water, the optical properties of which were characterized by means of spectroscopic methods. The supramol. structure of the aggregates is investigated by means of cryo-transmission electron microscopy, cryo-electron tomog. and AFM, revealing extended sheet-like aggregates for chiral enantiomers and nanotubes for the mesomer, resp., whereas the conformer forms predominately needle-like crystals. The experiments demonstrate that the aggregation behavior of compounds can be controlled solely by head group stereochem., which in the case of enantiomers enables the formation of extended hydrogen-bond chains by the hydroxyl functionalities. In case of the achiral meso form, however, such chains turned out to be sterically excluded.

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