Tag: 100-200

Thermodynamic and kinetic studies of glucose mutarotation by using a portable personal blood glucose meter was written by Perles, Carlos Eduardo;Volpe, Pedro Luiz Onofrio. And the article was included in Acta Chimica Slovenica in 2009.Safety of (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate This article mentions the following:

A thermodn. and kinetic study of the mutarotation reaction of D-glucose in aqueous solution was carried out using a portable personal blood glucose meter. This phys. chem. experiment is proposed as an alternative to classical polarimetry. The glucose meter allows the indirect monitoring of the mutarotation process in water, by using an enzymic redox reaction. The test strips of the glucose meter contain glucose dehydrogenase which converts β-D-glucose into D-glucolactone. This reaction selectively converts glucose and generates an elec. current in the glucose meter which is proportional to the glucose concentration This experiment allows the teacher to explore the kinetics and thermodn. of the mutarotation of D-glucose and, moreover, the stereospecificity of enzymic reactions. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Safety of (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Tetrahydropyrans are useful synthons for biologically important compounds. The most notable anticancer agent, bryostatin, and eribulin are marine macrolides having intriguing tetrahydropyran and furan motif. Safety of (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Conducting Redox Polymer-Based Reagentless Biosensors Using Modified PQQ-Dependent Glucose Dehydrogenase was written by Habermueller, Katja;Reiter, Sabine;Buck, Harvey;Meier, Thomas;Staepels, Johnny;Schuhmann, Wolfgang. And the article was included in Microchimica Acta in 2003.Related Products of 14431-43-7 This article mentions the following:

Reagentless, oxygen-independent glucose biosensors based on an Os-complex-modified polypyrrole matrix and on soluble PQQ-dependent glucose dehydrogenase from Acinetobacter calcoaceticus are described. As the soluble form of glucose dehydrogenase from Acinetobacter calcoaceticus is a hydrophilic enzyme with a pos. net charge, its entrapment into the pos. charged hydrophobic polypyrrole film is much more complicated than that of the corresponding membrane enzyme or the neg. charged and very stable glucose oxidase. Possible ways for using soluble PQQ-dependent glucose dehydrogenase in combination with conducting polymer films are seen in the modulation of the enzyme properties by covalent binding of suitable compounds to the protein shell together with the adjustment of the properties of the conducting polymer film. This can be done by neutralizing the net charge of the protein and/or optimizing the electron-transfer pathway between enzyme and electrode surface by covalent binding of suitable redox relays to the protein surface. In addition, methods for increasing the hydrophilicity of the polymer film, such as the co-entrapment of high-mol. weight hydrophilic additives and copolymerization of hydrophilic pyrrole derivatives are presented. It is demonstrated that the replacement of the parent monomer pyrrole by a suitable hydrophilic pyrrole derivative facilitates the entrapment of the modified soluble PQQ-dependent glucose dehydrogenase into the Os-complex-modified polymer and hence allows for the development of reagentless biosensors. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Related Products of 14431-43-7).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Numerous natural products have tetrahydropyran skeleton as the building block for designing new natural products and their derivatives e.g. aplysiatoxins, avermectins, oscillatoxins, talaromycins, latrunculins and acutiphycins. The Prins reaction of homoallylic alcohols with aldehydes afforded an alternative method for the preparation of tetrahydropyrans.Related Products of 14431-43-7

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Observation of process of melting of glucose and lactose on heating by differential scanning calorimetry and microscopy was written by Sakamoto, Kaoru;Kishihara, Shiro;Sakuda, Harumi;Miura, Kayoko;Koizumi, Yae;Yamamura, Eiko. And the article was included in Seito Gijutsu Kenkyu Kaishi in 2008.Electric Literature of C6H14O7 This article mentions the following:

We have reported that in spite of the fact that the purity of com. granulated sugar is higher than 99.9% the sugars from different refineries have different m.ps., and also that they showed different melting profiles and different colored brown. These facts are a very curious phenomenon, when considering that crystal substances generally have their own specific m.ps. We looked at crystals of D-glucose and D-lactose instead of sucrose in this study. By differential scanning calorimetry (DSC) and microscopy, the process of melting by heating the two sugar crystals was observed Also by using a scanning electron micro-scope, the surface of the crystals was observed The m.p. of α-D-glucose monohydrate is accepted as 83° in the literature. For the α-D-glucose monohydrate used in this study, three peaks on the DSC endothermic curve were observed at around 80°, 122° and 154°. However, on heating the α-D-glucose monohydrate, the crystal did not melt at 83°, and melted partially at 126° and completely at 158°. The temperature, at which the crystal melted completely, was close to m.p. of β-D-glucose anhydride in the literature. The m.p. of α-D-lactose monohydrate in the literature is 201-202°. The DSC-endothermic curves for the crystals of the α-D-lactose monohydrate used in this study had two sharp peaks at 146° and 219°. In the microscopic observation, melting of the crystals was not observed at the temperature (146°) of the first peak on the DSC endothermic curve nor at the m.p. (201-202°) reported in the literature. It was observed that α-D-lactose monohydrate began to turn brown, and began to partially melt at around the second peak (219°) and completely melted at 229°. After the α-D-glucose monohydrate and the α-D-lactose monohydrate were dried at 105° and 120°, resp., the resp. first peaks had a tendency to disappear or become small. On the observation with scanning electron microscope, both of the dried mono-hydrates had a lot of cracks on the crystal surface, which were possibly caused by the release of water mols. from the interior of the crystals. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Electric Literature of C6H14O7).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Dihydropyrans and tetrahydropyrans are examples of cyclic ethers widespread in nature. The most notable anticancer agent, bryostatin, and eribulin are marine macrolides having intriguing tetrahydropyran and furan motif. Electric Literature of C6H14O7

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Distribution of radiation-induced radicals in some hexoses was written by Neubacher, Harald. And the article was included in Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, Biochemie, Biophysik, Biologie in 1969.Reference of 14431-43-7 This article mentions the following:

α-D-Glucose, D-glucose monohydrate, β-D-glucose, D-glucuronic acid, and α-D-methyl glucoside crystals were x-ray irradiated (2-10 megarads) at 20° in air. ESR spectra were recorded. With increasing dose, relaxation times (T1) decreased. With increasing field strength, saturation was quickly approached. Saturation concentration of radicals increased with dose. Maximum signal was obtained at microwave field strength H11 = 2/[γ(T1T2)1/2], where γ is the gyromagnetic ratio for free electrons, T1 and T2 are spin-lattice and spin-spin relaxation times, resp. The dependence of relaxation time on radical concentration is presented graphically. T1 is of the order 10-5 sec and is concentration dependent. The radicals form clusters along ionization bands, and with increasing dose, local concentrations of the radicals become very large and the relaxation times then become constant In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Reference of 14431-43-7).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Tetrahydropyran is a useful synthetic intermediate. Tetrahydropyranyl (THP-) ethers derived from the reaction of alcohols and dihydropyran are common intermediates in organic synthesis. One classic procedure for the organic synthesis of tetrahydropyran is by hydrogenation of the 3,4-isomer of dihydropyran with Raney nickel.Reference of 14431-43-7

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Catalytic hydrogenation of fine chemicals: sorbitol production was written by van Gorp, K.;Boerman, E.;Cavenaghi, C. V.;Berben, P. H.. And the article was included in Catalysis Today in 1999.Quality Control of (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate This article mentions the following:

Historically, skeletal nickel is the catalyst of choice in the production of sorbitol on industrial scale. A disadvantage of the use of skeletal nickel in the hydrogenation of glucose containing feedstocks to sorbitol, is the fact that a part of the nickel leaches. As a consequence, purification of the sorbitol is required, which renders this process economically less attractive. To meet the demand for non-leaching catalyst systems, ruthenium on carbon catalyst are presently becoming more important. In this paper, a comparison is made between different 5% Ru on carbon catalysts in the hydrogenation of a dextrose monohydrate and a very high maltose feedstock. The influence of the carbon support, the ruthenium metal location, and the applied ruthenium precursor are investigated. For comparison reasons, both skeletal Ni and Ru catalysts have been applied in the hydrogenation of dextrose to sorbitol. The effect of reaction temperature and pressure during the hydrogenation of a very high maltose containing feedstock is also investigated. It is shown that Ru catalysts are suitable alternatives for skeletal Ni catalysts in respect to re-usability, activity and selectivity. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Quality Control of (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Tetrahydropyran is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and dyestuff. The bismuth chloride-assisted cross-cyclization between homoallylic alcohols and epoxides provided various benzyl tetrahydropyran derivatives. The reaction afforded good yields of desired products and occurred under mild conditions.Quality Control of (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Condensed matter effects on the structure of crystalline glucose was written by Molteni, C.;Parrinello, M.. And the article was included in Chemical Physics Letters in 1997.Synthetic Route of C6H14O7 This article mentions the following:

By means of ab initio simulations based on the Car-Parrinello method, we have calculated the crystalline structures of α-D-glucose, α-D-glucose monohydrate and β-D-glucose. The good agreement with the available exptl. data gives us confidence in the applicability of the method to carbohydrates and opens the path towards the investigation of more complex problems, where a quantum mech. description is essential. Condensed matter effects are discussed by comparing the structures of the glucose mol. in the crystalline and gas phases. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Synthetic Route of C6H14O7).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Numerous natural products have tetrahydropyran skeleton as the building block for designing new natural products and their derivatives e.g. aplysiatoxins, avermectins, oscillatoxins, talaromycins, latrunculins and acutiphycins. The most notable anticancer agent, bryostatin, and eribulin are marine macrolides having intriguing tetrahydropyran and furan motif. Synthetic Route of C6H14O7

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Stereospecific synthesis of (±)-β-santalol was written by Sato, Kikumasa;Miyamoto, Osamu;Inoue, Seiichi;Honda, Kiyoshi. And the article was included in Chemistry Letters in 1981.SDS of cas: 13417-49-7 This article mentions the following:

BrCH₂CH₂CH:CMeCH₂OAc, obtained in 4 steps from 5,6-dihydro-2H-pyran-2-carboxaldehyde, reacted with the bicycloheptanecarboxylate I to give II, (R = CO₂Et, R¹ = Ac), whose reduction with (Me₂CHCH₂)₂AlH followed by bromination and LiAlH₄ reduction of II (R = CH₂Br, R¹ = Ac) gave (±)-β-santalol (II, R = Me, R¹ = H). In the experiment, the researchers used many compounds, for example, 5,6-Dihydro-2H-pyran-3-carbaldehyde (cas: 13417-49-7SDS of cas: 13417-49-7).

5,6-Dihydro-2H-pyran-3-carbaldehyde (cas: 13417-49-7) belongs to tetrahydropyran derivatives. In organic synthesis, the 2-tetrahydropyranyl group is used as a protecting group for alcohols. The reaction of tertiary 1,4- and 1,5-diols with cerium ammonium nitrate at room temperature gives tetrahydrofuran and tetrahydropyran derivatives in high yield and stereoselectivity. Various fragrant compounds have been synthesized using this method.SDS of cas: 13417-49-7

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Thermal behavior of carbohydrates studied by heat flow calorimetry was written by Raemy, A.;Schweizer, T. F.. And the article was included in Journal of Thermal Analysis in 1983.Application of 14431-43-7 This article mentions the following:

Heat flow calorimetry was used to study the thermal behavior of different carbohydrates between 20° and 270°. The samples were analyzed by heating in sealed cells. The temperature range in which exothermic reactions, due to thermal decomposition, occurred varied widely depending on the type of carbohydrate investigated. Reaction enthalpies of 44 sugars and polysaccharides are given. Endothermic phenomena, such as fusion of vaporization of crystallized water, were also observed; fusion temperatures and enthalpies of 34 sugars and sugar alcs. are listed. Calorimetric curves showing crystallization of amorphous sucrose, cellobiose and lactose are also presented. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Application of 14431-43-7).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Tetrahydropyran is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and dyestuff. 2-(Arylmethylene)cyclopropylcarbinols could be converted to the corresponding tetrahydropyrans stereoselectively in the presence of Brønsted acids under mild conditions. A plausible Prins-type reaction mechanism has been proposed.Application of 14431-43-7

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Studies on bioethanol production with thermo tolerant yeast isolates, their co-cultures using african wild cocoyam as feedstock was written by Chukwudi, I. Nnamchi;OkeChukwu, U. Nwachi;Ifeanyi, A. Ndubuisi;Onyetugo, C. Amadi. And the article was included in Asian Journal of Biotechnology and Bioresource Technology in 2021.Synthetic Route of C6H14O7 This article mentions the following:

In this work different ways of optimally producing bioethanol at various pH with thermotolerant yeasts, their cocultures using a non-human edible starchy food as feedstock was examined African wild cocoyam, Xanthosoma roseum, sourced from abandoned farmlands in Obukpa, Nsukka, Nigeria was used as the substrate, while strains of Kluyveromyces marxianus, Pichia stipitis were used to ferment them. First the tubers were gelatinized by boiling under pressure above 100°C before hydrolysis with concentrated H₂SO₄. The hydrolyzates were then fermented at 35°C with the thermotolerant yeasts for five days at different pH. Results obtained showed that gelatinized sample of the substrate gave optimum glucose yield when hydrolyzed with 1M H₂SO₄ for 60 min. Kluyveromyces marxianus produced more ethanol than Pichia stipitis at all the four fermentation pH values tested. However, optimum ethanol production was obtained when the two yeast strains were used as coculture at pH 4.5. The peak time for ethanol production was 96 h for the individual yeast cultures while that of their coculture was 72 h. The results of the study indicated that wild cocoyam is an excellent feedstock for bioethanol production with many advantages including being nonedible, thereby eliminating concerns for food security, containing high amount of carbohydrate. The study also revealed that fermenting sugar hydrolyzates with a coculture of microorganisms during bioethanol production is a more efficient process than using individual cultures. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7Synthetic Route of C6H14O7).

(2S,3R,4S,5S,6R)-6-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol hydrate (cas: 14431-43-7) belongs to tetrahydropyran derivatives. Dihydropyrans and tetrahydropyrans are examples of cyclic ethers widespread in nature. 2-(Arylmethylene)cyclopropylcarbinols could be converted to the corresponding tetrahydropyrans stereoselectively in the presence of Brønsted acids under mild conditions. A plausible Prins-type reaction mechanism has been proposed.Synthetic Route of C6H14O7

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics

Nonamethinecyanines with cyclic groups in the polymethine chain was written by Slominskii, Yu. L.;Radchenko, I. D.;Efimenko, N. I.;Tolmachev, A. I.. And the article was included in Ukrainskii Khimicheskii Zhurnal (Russian Edition) in 1980.Formula: C6H8O2 This article mentions the following:

Six bridged tetracarbocyanines (I; R = H or RR = benzo; R¹ = Me, Et; X = I, ClO₄; X¹ = S, CMe₂; X² = direct link, CH₂, O) with λ_max ranging from 855 to 915 nm were prepared by condensation of the resp. II with heterocyclic quaternary compounds The II were prepd from PhNMeCH:CHCH:N⁺MePh I^– [63899-31-0] and the appropriate cyclic aldehydes. The (CH₂)₂, (CH₂)₃, and CH₂OCH₂ bridges in I cause bathochromic shifts of 45, 128 and 15 nm, resp. In the experiment, the researchers used many compounds, for example, 5,6-Dihydro-2H-pyran-3-carbaldehyde (cas: 13417-49-7Formula: C6H8O2).

5,6-Dihydro-2H-pyran-3-carbaldehyde (cas: 13417-49-7) belongs to tetrahydropyran derivatives. Tetrahydropyrans are also used as important solvents, as chemical intermediate and as monomer for ring-opening polymerization. The reaction of tertiary 1,4- and 1,5-diols with cerium ammonium nitrate at room temperature gives tetrahydrofuran and tetrahydropyran derivatives in high yield and stereoselectivity. Various fragrant compounds have been synthesized using this method.Formula: C6H8O2

Referemce:
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics