Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, Formula: C12H22O11.
A spectrophotometric and (1)H NMR kinetic study of the reactions of cis-[PtPh2(CO)(SEt2)] with an extended series of dinitrogen chelating ligands (N-N) of widely different steric and electronic properties has been carried out in dichloromethane solution. The contemporary presence in thestarting substrate of a labile (SEt2) and a relatively inert (CO) ligand in trans to firmly bonded phenyl groups makes it possible to distinguish three different reactivity patterns, according to the nature of the bidentate ligands used. Relatively stable open-ring species of the type cis-[PtPh2(CO)(N-N)] were isolated with the long chain ligand 1,4-diaminobutane and with N-phenyl-1,2-diaminoethane in which one of the two nitrogens exhibits very low basicity and considerable encumbrance. For the other dinitrogen ligands, the relative magnitude of the rates of attack atthe metal and of ring closure dictates whether the chelate formation isseen as a simple conversion of the starting complex into the final chelate [PtPh2(N-N)] or as a two stage process with evidence for the formation of an open-ring species. With rigid or highly sterically hindered ligands such as 2,2′-dipyridyl, 1,10-phenantroline, dicyclohexylethylenediimine or N,N,N’,N’-tetramethylethylenediamine a single stage process fromthe starting complex to the final chelate compound was observed. The rate determinig step is thought to involve slow dissociation of SEt2 from the complex followed by fast ring closing. With 1,2-diaminoethane, 1,3-diaminopropane, 2-aminomethylpyridine, 2-aminoethylpyridine, 2,2′-dipyridylamine and 2,2′-dipyridylsulfide a slow ring closure of the open-ring complex follows the fast entry of the first end of the ligand. The substrate shows a remarkable selectivity between the two nucleophilic ends of an unsymmetrical bidentate ligand with a clear preference for the most basic and the less hindered end. Open-ring reaction intermediates cis-[PtPh2(CO)(N-N)] were characterised in solution by their IR, (1)H and (13)CNMR spectra and their spectroscopic characteristic are compared to those of the parent amine and phosphine compounds. The final chelate compounds [PtPh2(N-N)] were either isolated as solids or characterised in solution.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C12H22O11. In my other articles, you can also check out more blogs about 499-40-1
Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics